Create a dedicated configuration file /etc/dhcp/dhcpd6.conf for the IPv6 part of the dhcpd. Note, that the router requires to have a interface configured with an IPv6 address out of the defined subnet.

default-lease-time 600;
max-lease-time 7200; 
log-facility local7; 
subnet6 2001:db8:0:1::/64 {
        # Range for clients
        range6 2001:db8:0:1::129 2001:db8:0:1::254;

        # Range for clients requesting a temporary address
        range6 2001:db8:0:1::/64 temporary;

        # Additional options
        option dhcp6.name-servers fec0:0:0:1::1;
        option dhcp6.domain-search "domain.example";

        # Prefix range for delegation to sub-routers
        prefix6 2001:db8:0:100:: 2001:db8:0:f00:: /56;

        # Example for a fixed host address
        host specialclient {
    		host-identifier option dhcp6.client-id 00:01:00:01:4a:1f:ba:e3:60:b9:1f:01:23:45;
        	fixed-address6 2001:db8:0:1::127;
    	} 
} 

Note that the ”dhcp.client-id” no longer belongs to a MAC address, an unique ID is used instead! ”dhcp6c” (see above) uses the file /var/lib/dhcpv6/dhcp6c_duid (would be created during first start, if not existing) as unique identity. It's a 14 byte long identifier, starting with a 2 byte length information (usually ”0x000e”):

# hexdump -e '"%07.7_ax " 1/2 "%04x" " " 14/1 "%02x:" "\n"' /var/lib/dhcpv6/dhcp6c_duid 0000000 000e 00:01:00:01:4a:1f:ba:e3:60:b9:1f:01:23:45:

Start server in foreground:

# /usr/sbin/dhcpd -6 -d -cf /etc/dhcp/dhcpd6.conf eth1 
Internet Systems Consortium DHCP Server 4.1.0 
Copyright 2004-2008 Internet Systems Consortium. 
All rights reserved. 
For info, please visit http://www.isc.org/sw/dhcp/ 
Not searching LDAP since ldap-server, ldap-port and ldap-base-dn were not specified in the config file 
Wrote 0 leases to leases file. 
Bound to *:547 
Listening on Socket/5/eth1/2001:db8:0:1::/64 
Sending on   Socket/5/eth1/2001:db8:0:1::/64